Chuffer:
For locomotive cylinders, depending on what was visible on the full-size, you may be able to disguise the oiling-plugs in the covers as dummy (even working??) relief-valves.
Perhaps easier on narrow-gauge styles. On his 7-1/4" g version of the Kerr-Stuart 'Wren', Ken Swan specified replicas of the displacement-lubricators on the valve-chest covers, as cold oil feeders.
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Dave:
I think there are water-treatment compounds for copper boilers, to minimise scale; though that intended for steel probably won't hurt. It can give problems with fittings, by clogging small pipes, passages and injectors though, if used a bit too enthusiastically.
I'm a bit confused by your question about water-treatment. I assume you mean only in the boiler, but I doubt it would do any good in the cylinders. For one thing it normally stays in the boiler, for another it would need a lot of water (heavy priming) to put enough in the cylinders to coat the iron – defeating the object and not exactly good for the engine.
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A friend used to keep his 7-1/4" g., NG loco, a Hunslet I think, in a wooden garden shed. He used an ordinary garage inspection-lamp with low-wattage bulb in the firebox, and draped an old blanket over the whole loco. It not only worked for the engine. A mouse made himself a very cosy little nest on the footplate!