The tip is held in by the end of the long shroud over the heating element. Unscrew the big nut at the bottom, it shouldn't be very tight (mine is a knurled nut that can only be done finger tight), pull off the shroud and pull the tip out from its recess.
If the tip hasn't been changed for many years they tend to be very tight due to stuff build up where it sits in the socket. When you get a new tip a little cleaning will most likely be needed. Back in the day Weller ( I think ) supplied a grease to prevent this locking. At RARDE we had something to wipe on.
When you get a new tip make sure the temperature range is correct for the solder you intend to use. Mine are for old style cored solder, of which I have a 3 lifetimes stash, and struggles with the modern stuff. Undoing a joint is OK but if I had to solder a board with new style solder I'd get a new tip of appropriate rating.
Clive