I bought some ali welding wire from the Swedish Chef at the Harrowgate show.
He demonstrates and then invites you to have a go, and I did, and it works! It requires a different technique as has been said, but it seems easy enough to pick up. He uses a torch, not an iron, but it's not a big flame, and there is little other kit, just a spike to scratch the oxide off the alloy.
The wire seems very expensive at about about £25.00 a metre IIRC but he measures out "Swedish Metres" by stretching out his arms, and he is quite tall, so you get about 6 feet if you buy a metre. And it seems to be reusable.
He insists it welds, forming an alloy with the ali being joined, and I don't know if that's right or not, certainly thin ali sheet melts right through when you joint something to it, you can see the imprint on the reverse of the sheet. Which does not seem like soldering which I always think of a a surface effect like glue.
So, if you are going to the show, find his stand and try it for your self and buy a piece to take home.
Rod