Posted by SillyOldDuffer on 24/03/2022 16:36:21:
Knowing a bit of chemistry might clear some fog.
The Paraffins were a family of chemicals containing only Hydrogen and Carbon in single chain molecules. In modern Chemical parlance, they are called Alkanes.
The chains can be very long, and although the chemistry of all the members is similar, as the weight of the molecules increases, they go from gases to solids, via vapours, light liquids, heavy liquids, greases, sticky goo and waxes.
The first 4 are all fuel gases, delivered as compressed liquids in cylinders.
The heaviest alkane listed by Wikipedia is Tetrapentacontane (C54H110), a solid which boils at just under 600°C. Might find it in Bitumen.
Heavy Alkanes dissolve in lighter Alkanes, so the lighter liquid mixtures are often used as solvents.
Petrol, Naptha, White Spirit, Paraffin, Jet Fuel and Heating Oils are all mixtures of nearby Alkanes, where each group is heavier than the one below.
Petrol contains, amongst other things, mostly very light easily vaporised alkanes like Octane. An excellent solvent, but best avoided because the fumes are poisonous and a serious explosion risk, easily ignited by a static spark.
White Spirit is a mixture of Alkanes between Nonane (9 carbon atoms) and Dodecane (12 carbon atoms). The members are still light Alkanes, but much less easily vaporised than petrol. White Spirit is safer! The heaviest member (Dodecane) boils at -9.6C, so White Spirit shouldn't leave much residue behind.
According to Wikipedia, dodecane boils at 214C. -9.6C is pretty improbable, it would flash off at room temperature, and white spirit doesn't