DC I can’t put screws or dowel pins into the plate through from the reverse (front) side as that is where the circular T slot lies
I edited my post to add a photo, possibly after you read it, but this morning the photo has disappeared.
You can avoid bolting from the front. The only place you would drill for bolts (or pins) would be in a part of the cast item that is currently painted grey. For each half, one bolt in the underside; one bolt on the sloping side and one bolt on the (less sloping) top.
For the steel stubs that go into the casting lattice holes, I would aim for a nominal 2mm clearance on all five sides and maybe look for a fluid epoxy that I could inject once the two parts are assembled and aligned.
As above, drilled and reamed holes with mild steel pins loctited in and then the surface filed flush with the casting would look tidy. Using pins would also expand your positioning options – with bolts coming in from three directions, you have to make sure they do not clash and that ther eis a minimum distance between the female threads.
Perhaps as a modification to the angle you suggest, mill a small flat on the underside that is perpendicular to the sawn face. Then make a step on the welded fabrication. The casting would sit on that step. That would also greatly assist alignment (reduce your fixturing requirements) as it stops the assembly trying to rotate.