A two-stroke piston will have pegged rings, no oil control rings or piston oil slots, and quite likely, a top ring which is L shaped in secton, fitted at the very top. It will also be likely to have cut-aways in the skirt below the gudgeon pin holes, if post ww2, and if pre ww2 or an outboard engine, the top of the piston will be an odd shape, not at all flat or lightly domed.
A four-stroke piston will have a land above the top ring, and a third (or fourth) ring slotted so that oil can drain back inside. The sides of the piston beween the thrust faces (ie around the gudgeon holes) may well be well back from the bore, if it was for a high performance engine, and the top of the piston is likely to be raised in the middle, and with cut-aways for valve clearance.
If what you need is a quirky ashtray, the two-stroke is better as it has no oil slots. If you need a source of a sensible alloy to melt down, light alloy pistons can be a good choice. In this case, avoid forged pistons as they won't melt down so nicely. Before ww2 many engines had cast iron pistons, though. If for a different purpose, helpful comments are going to be in short supply as we have not been told the purpose for which the piston is needed.
Regards, Tim
Edited By Tim Stevens on 24/11/2022 16:00:30