A rubber or synthetic with a fabric reinforcing layer (maybe Kevlar) would be ideal, specially if concentric corrigations could be included. About 2 yrs ago, I was thinking of making up a mold to make some experimental diaphragms. Up to that time I had been making molds for rubber components for vintage millitary vehicles, mainly Willys Jeeps. There are quite a number of different rubbers for different uses. I lost my molds in Christchurch's earthquake, I don't know even now if they have been salvaged, about 6 or8 molds at a value of over $NZ1000 if they had been professionally made. Ian S C