The problem you are likely to face is 'electrolytic corrosion'. This involves two different metals in contact, and damp or wet conditions. This creates a feeble, but continuous, electric cell – and the more reactive* metal is corroded most. With iron and aluminium, the iron will rust a bit but the Aluminium will corrode to a white jelly of aluminium oxide. Separating the two metals will only help if there is NO contact – iron rivets in aluminium and you've no chance. Unless you live is Death Valley etc. Or you could completely cover the rivetted area with a permanent layer of insulator bonded on all over. Not easy.
If you use rivets of aluminium (ideally the same recipe as the rim) then you have a better chance, but the, steel spokes will then become the problem. Aluminium spokes will then help, and lift the area away from the main source of damp.
* yes, normally we think of aluminium pans etc as not reactive. This is because of a surface layer of impervious oxide which prevents the metal showing. Electricity will cut through this layer, and the corrosion starts in earnest.
And copper rivets, or brass, will be worse than steel ones – sorry!
Cheers, Tim