Hi Paul, yes it is like you say Hydrogen cracking but is often refered to as “Cold Cracking”. In Leaded steel atomic Hydrogen is drawn into the HAZ, but Hydrogen is insoluble in ferrite (iron) so on cooling molecular Hydrogen is rejected and forms high pressure pockets, crystal voids, Hydrogen entrapment. These Hydrogen voids reduce the strength and cracks form, and lead to sudden failure some days after it has been welded.
No they are not limited to thickness, but a smaller section will achieve enough heat for this effect not to occur so readily. In my old company I used to work for, we used to weld shafts up to 4″ in diameter into conveyor belt drums. At one piont the turner who used to make them started to use leaded free cutting steel, and the problems of them snapping off at the weld started. Pre heating and post heating prevented this, but was more costly and time consuming, nor was very practical to implament. Such shafts were subsequently made from non free cutting steels and the problems no longer occured.
Sulphur in steels is very prone to “Hot cracking” due to iron sulphide forming in steels above 0.04%. Most steels are made with less than this, but it can be imported into the weld from a variety of sources. Iron sulphide melts at about 1000 C, if the steel is cooled below 980 C the Iron sulphide solidifies. Due to high contraction rates and the weak nature of iron sulphide, fracture occurs on solidification of the weld. Thankfully I haven’t had the pleasure of welding sulphur steels.
MIG welding is regarded as low Hydrogen. But as I’ve said, its best to aviod welding free cutting steels, especially leaded or sulphur ones.
Regards Nick.
P.S. Andrew may not be OT, but I feel it is related. Can be disheartening turning something up nicely and then welding it into somrthing else only to find it failing later on.
Edited By Nicholas Farr on 11/03/2011 11:33:10