Lets clear something up from square 1
The 2%, 5% and 15% silver alloys are not "silver solders". They are copper (Cu) phosphorus (P) alloys for the fluxless brazing of copper in air.
The 45% silver alloy is a silver solder that contains copper, zinc and possibly cadmium or tin.
Generally, increasing silver contents lowers the effective liquidus (temperature at which a joint can be made) and improves the ductility of the alloy itself.
It makes very little difference to the solidus (temperature at which the alloy freezes)
Data from the International Standard for Brazing Materials ISO 17672 shows the following melting ranges:
2% 645 – 825 or 643 – 788 dependent on the phosphorus content. Ductility 5%
5% 645 – 815 or 643 – 771 dependent on the phosphorus content Ductility 6%
15% 645 645 – 800 Ductility 25%
The ductility figures are as stated by manufacturers.
The 2%, 5% and 15% alloys can be used to join copper alloys but need an external flux. Use a suitable silver solder flux to suit the heating cycle.
In reality it makes little difference to the joint ductility for the model engineer because the copper is fully annealed at brazing temperature and as usual the parent material will fail first.
A word of caution.
DO NOT USE THESE ALLOYS TO JOIN COPPER OR ITS ALLOYS TO NICKEL OR FERROUS ALLOYS. They form brittle inter-metallic compounds in the parent materials that will lead to catastrophic joint failure.
DO NOT USE THESE ALLOYS IN HOT SULPHUROUS ATMOSPHERES eg COAL FIRED BOILERS. The sulphur will go through the joint like a hot knife through butter!
Keith