I use 45% silver solder for joining steam fittings and fabricating valves but it is expensive.
15% Silver alloy rods are normally used for plumbing applications like copper pipe, hot water tanks, plumbing fittings, etc. Excellent for gap-filling where close fit-up does not exist, and where thermal expansion and service vibration are involved. Melting Range: 645-800°C.
45% silver alloy rod for general purpose, high-strength joining of all ferrous and non ferrous metals, including steel, stainless-steel, copper, brass, nickel, etc. High fluidity & rapid capillary flow, good choice where parts have a close fit. . Melting Range: 640-680°C. (used for making copper boilers)