I have made lots of full size stationary engine valves,a lot of original valves have a material similar to siver steel for the stems and cast iron heads,Amancos and some ruston hornsbys for example,for very small engines the cast iron head would probably not work,though a silver steel stem would be round ,accurate and strong,so why not make the head from stainless steel and thread the component parts and screw them together and lightly rivet over the stem where it protudes through the head,then set the valve stem up in a lathe collet and very carefully skim the seating face of the valve with a very sharp HSS tool. Making a valve from solid rod is not a good idea as the inner core is not very strong when getting down to small diameters,automotive valves get over this problem by forming or forging the head on the valve. The Amanco open crank engine valves also have a valve seat angle of 45 degrees,they work and seal very well ,though often regarded as cheap and crude American engines ,for their time they were a very good engine which started easily ,would run in an absolutely worn out condition,and was an example of lots of capital poured into machines and tooling to produce a very cheap good product from day one of manufacture,the interchangeability of componens was very good,and having made lots of spares,never had a customer complaint about parts not fitting.