Hello Brian
It looks like Jason has a point. From the picture it looks like the alloy has been overheated. The "gas" coming off the alloy (if it is easiflo – and you don't know?) is likely to be cadmium fume.
STOP NOW!
RE-EXAMINE YOUR HEATING TECHNIQUE
I suspect that you are preferentially heating the alloy. Steel does not conduct the heat quickly into the joint area. The flux doesn't work and the alloy doesn't penetrate. So you then heat the alloy to get it to flow. Ring any bells?
Heat the joint. Not the alloy.
Get the joint hot. Watch the flux to see what joint temperatue you have. Let the alloy get its heat from the workpiece.
Fit a smaller burner than the Sievert 2901 that you are using. Be patient while heating. Make sure that the joint is up to temperature.
Change to a cadmium free silver solder.
Burners, alloys and technical information in an excellent book is available from CuP Alloys on line or at Ally Pally this week.
Take care.
Keith
PS You don't get information like this from ebay, car boots or many other sellers of silver solder.
What has your supplier had to say? Let me guess!!!!!!!!!!