If you need washers, use annealed copper washers, you can make your own. reanneal when replacing them, after taking the fitting out and putting it back.
Aluminium will help prevent corrosion on a asteel boiler, working as a sacrificial annode, zinc is even better.
On the cooling system of one of my hot air engines I ended up with a copper hopper for the water, and decided to use some aluminium fins imersed in the water, and exposed to the air for extra cooling. One day I , for some unknown reason, put the volt meter on the aluminium and the copper, result .5 volt, nothing much as current goes. Ian S C