(Second attempt to post this, I was sure I was logged in, hit the post button only to be informed that you must be logged in to use this feature so here is a much shortened version)
One or two points of fact (I hope)…
Almost any metal will burn if it is sufficiently finely divided and mixed with air or oxygen. The classic chemistry demonstration was pyrophoric lead made by heating lead tartrate and excluding oxygen as the lead dust cooled. This powder would spontaneously burst into flames when poured from the phial ito the air. The white sparks seen when F1 cars bottom out are the result of titanium being abraded away from the underside skid plates. (probably see lots more of those next season with the banning of refuelling during the races)
So I am not surprised to learn that titanium swarf can catch fire. I know of an incident in a local engineering firm (now, alas, closed) where an expensive CNC lathe was destroyed by a magnesium fire.
I suspect there are more issues than inflamability surrounding machining titanium as I have tried drilling holes in the stuff and find it work hardens like some stainless steels.
Minor point, but when magnesium burns in air the main product is white magnesiun oxide ( and smaller amounts of magnesium nitride and possibly trace amounts of carbon) I would not worry too much about the basic nature of this oxide as it is the active ingredient in many antacids used to treat indigestion (Milk of Magnesia)
Carbon Tetrachloride is very nasty and should be avoided at all costs. It is thermally decomposed to carbonyl chloride, also known as phosgene. The mustard gas reference is an understandable misconception as both were used in chemical warfare. The long term dangers of carbon tetrechlorde include cancers so find another safer solvent.
In general, treat all organic solvents with respect. They are miscible with the fatty membranes that surround cells, especially nerve cells in your body so it should be no surprise that they are bad news. I remember seeing glue sniffers at Birmingham New Street station in the late 1970s. An image that should serve as a reminder of the dangers of solvents.
A couple of things that have not be mentioned yet in this thread are cadmium (found in Easyflo No.2 silver solder) and the dangers of welding galvanised steel.
I remember a lot of information in the Model Engineer about the nature of the dangers from cadmium in silver solders. As I recall there was a fatality where the engineer had been engaged in silver soldering, but I don’t know if it was the cadmium to blame. I think the advice at the time was to avoid cadmium bearing alloys, but if you needed to use cadmium bearing alloys to not use oxy-acetylene (too hot for silver brazing anyway) and to work in a well-ventilated space. I think Tubal Cain published some estimates of the air-bourne levels of cadmium that seemed very low as long as common sence precautions were followed, but I wonder how they stand up against modern advice. Cadmium is a nasty cumulative poison and suspected carcinogen.
Welding galvanised steel is another bad idea.
Bob