Under no circumstances should an alloy containing phosphorus eg Rolot S2, S5, Silbralloy, Silfos be used to braze copper that may come in contact with hot sulphur bearing atmospheres. The sulphur will go through the joint like a hot knife through butter!
Equally these alloys should not be used to braze copper to steel or any non-ferrous alloy containing nickel.
The phosphorus forms a very brittle intermetallic compound with iron and nickel. For more information on this point investigate the disaster associated with the submarine USS Thresher.
Keith
PS in gas fired boilers – no problem. All copper/copper joints in your central heating boiler are made with these alloys.
Edited By CuP Alloys 1 on 12/02/2014 23:59:23