Posted by Mick B1 on 02/03/2021 11:43:16:
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I've found these guns a rather obscure area of ballistic history.
I've never properly understood why they had such massive reinforces ("coils" ) around the chambers. Were they expecting massive pressure peaks from the black powder propellants? Seems a bit OTT in view of the 1300 -1600 ft./sec. MVs, …
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They are fascinating. The massive bottle shaped reinforces were indeed due to Black Powder. Gunpowder has many shortcomings as a propellant; the chemical reaction produces a lot of solid material that damages the bore, gives away the gun's position, and blinds the gunner who can't see through his own smoke. It also burns too quickly, producing excessive pressure at the breech, and the effect gets worse as the gun gets bigger.
Various things were tried to slow the burn down, such as using partly charcoaled wood, compressing the powder into large pellets, which could be as big as a fist, and shaping them to slow down the rate of combustion. One of my old books mentions a lady watching a salute at Portsmouth catching a fizzing pellet in her stacked up hair-do. Seems these guns sprayed burning pellets about like a shot-gun.
The efficiency of modern guns owes as much to chemistry as it does improved steels and design. Unlike gunpowder smokeless powders can be adjusted to burn at the optimum rate needed to accelerate a projectile up the barrel without over-stressing it. Artillery became much slimmer – thin walled barrels and no need for bottle reinforcing at the breech.
Didn't happen overnight. Propellant problems destroyed several French, British, Italian, and American battleships. Bulk smokeless powder is prone to spontaneous combustion unless carefully made from pure materials, stored in temperature managed magazines, tested regularly and with and rigorous observation of best before dates. Harbour accidents took the Iéna and the Liberté at Toulon, HMS Vanguard and HMS Bulwark in the UK, the Italian dreadnought Leonardo da Vinci, and probably the USS Maine, and the USS Iowa turret explosion in 1989.
Maine before and after pics from Wikipedia:
Many more ships were lost in action due to inadequate protection of the magazines, notably the British battlecruisers at Jutland and HMS Hood in WW2. Cordite packed an extra wallop, but it proved more likely to go bang by accident than the relatively weedy propellants used by other powers!
Lots more info here.
Dave