Hello again and very many thanks for the welcome, help and advice. I'm so pleased I wrote in with my query as I would normally have dove straight in and bought a 125mm Chuck and been left with a useless paperweight.
what I have done today is spent best part of my Sunday on that ARC website, I have ordered a 100mm 3 Jaw and a a C3 backplate. All looks straightforward, with the only niggle is the backplane is bored through at 26.5mm but the spigot on my Spindle is 30mm. There is no image of the backplate and a dimensioned drawing would be fantastic, I'm hoping that this has a machined recess in it otherwise I'm going to have a hell of a job mounting a 100mm diameter backplane into an 80mm chuck.
I have another lathe, an Eliott Unimate SL I have had this since 1982, and recently I had to rebuild the Motor as the internal suppressor developed an earth leak and kept tripping the House ELCB. I took lots of pictures of the job with a write up as a chap up in Scotland wanted to rebuild his. If anyone wants to do the same I will give you the information and any help needed. Beware though, this job is not for the feint hearted, bit like mending a ladies watch in a teacup!