The grainy look is typical of a fatigue failure as shown in this photo.
Looks like cast-iron, but isn't. The appearance is more to do with how it broke than what it's made of. An unbroken screw of the same material would look very different if it were sawn, faced, polished, and dipped in acid to highlight the grain structure.
Although Aluminium, Brass and Steel can be told apart by eye, much harder to identify particular alloys, especially if the internal structure has been altered by heat treatment or a breakage.
The screw-jaw is a low carbon steel, probably something a grade or two tougher than ordinary mild-steel. A XRF analyser would identify the alloy in a few seconds: found a new one on ebay, only £15,000!
Pratt Burnerd chucks in good condition are worth having. Might be fixable but I suspect Andrew's example will never be as good as new again! Probably scrap.
Dave