I'm a bit late to the party.
I've had great success using 2 pack urethane – it's as tough as old boots and can be coloured. Available in a range of hardness, I get mine from Bentley Advanced Materials, it isn't cheap but it is good quality – their colour pigments are UV resistant which is important for your application!
Silicone has a much lower resistance to hydrocarbons/oils/fuel – I wouldn't advise it on a car, but on the back lights, maybe ok?
I 3D print the moulds and give them a final finish (what ever is needed, a bit of sanding, a touch of filler, a coat of XTC3D and a final spray of release agent (as urethane is a very strong adhesive IIRC)
I cast a seal face on a 3D printed conical sealing head, using a 3D printed mold, for a 1 ton per hour pulverised coal injection machine running at upto 7 bar, the seal head is on the main bulk material inlet, I built the machine a few years ago, and it's still running today.