My son-in-law has a patio fabrication business. All products are powder coated. I help him out as required – like today. I am the "trades assistant!" All that education, skill and knowledge gained through life is not required to be a "trades assistant!"
All powder coating powder is not created equal. Some are better than others, and the price varies dramatically.
Also, metal preparation is critical, and as he only deals with new steel and aluminium. I cannot comment about exotic metals, but I know from only working with new steel and aluminium that cleanliness is very important.
Outdoor products – like a steel verandah or staircase hand rail he has galvanised – after fabrication, and before powder coating. There is a "wait" of at least a week between the "hand rail" returning from the galvaniser before it is powder coated. It is also cleaned before coating.
Oven temperature is very important. Not hot enough is a disaster, as is too hot. Manufacturers of "powder" specify a minimum temperature and baking time. Equally, a maximum temperature and time.
The point of my post is that to make a living, the powder coater you choose will have to be attuned to the material that "he" is working with, so I can see that when an "exotic" job comes along – which he has limited experience with that it can all go bad.
Not much help really, but it does give some view on a "practical coal face" experience.