I bought some Plasticote acrylic spray cans from Hobbycraft thinking it would be good, unfortunately it wasn't! While it adheres well the primer is difficult to flat and the (silver) top coat was very soft. Just picking the part up left fingerprints even after a good few hours.
Maybe I did something wrong, I followed the instructions though, but found it to be much harder to spray than normal car (Halfords) paint which I will try next time.
Haven't needed to spray anything else since as I bought some silver PLA and the Plasticote stuf went in the recycling bin…