The economics need looking at carefully; if this was the cheapest way of making oxygen everybody would be doing it!
- I see 2kg of Zirconium Dioxide costs £256.
- The paper discusses providing Medical Oxygen in Papua New Guinea. I think it can be assumed there isn't a local BOC just round the corner and cylinders have to be carried long distances over poor roads or flown in. High prices in the third world are likely due to transport and availability issues rather than the manufacturing cost of Oxygen.
My regional British hospital doesn't use BOC either! Makes its own Oxygen in a whopping big Air Liquification Plant that takes up as much space as my house and garden and is slightly taller. Presumably a big Teaching Hospital consumes enough high-grade oxygen to make it worth eliminating transport and third party costs. Economies of scale look to have failed my dinky little Cottage Hospital – it has Oxygen cylinders delivered by lorry.
I can see an Oxygen Concentrator would win if very low volumes of not very pure oxygen are needed, because it eliminates the cylinder hire, recharging and transport costs.
Cryro methods are more expensive the either the Zircona, Membrane, or Hydroylsis methods. But there are loads of gotchas. High purity Oxygen is most cheaply made by cryogenic processes, which also produces pure Nitrogen and pure Argon as valuable by-products. If there's a market for them, the Oxygen can be sold more cheaply than it cost to make. And when Hydrogen is made by hydrolysis, Oxygen comes off as the "free" by-product.
As is often the case in engineering, the right answer depends on money and circumstances.
Dave