Hi All, thanks for the various bits of information. I should have thought a bit more carefully about the operation of a VFD really, as it's fairly obvious that a single phase input could be rectified to DC, albeit with the potential to retain a few ripples.
I think I'll set it up to start gently and give the capacitors a chance to recover, though it's probably possible to replace these if absolutely necessary. I have a very large autotransformer that can be persuaded to give quite a range of voltages so I'll start small and work my way up. At the end of the day this was a freebie so it's not a calamity if it doesn't work, but it would be a real bonus if it does as it would mean i don't need to run an idler motor.
For a power supply my electrician is about to hook up a 40A radial circuit from the RCD-enabled distribution board, which will do for checking this out. This supply is ultimately intended for my rotary phase converter, but that is another project entirely (I may post on that elsewhere, as it's been an interesting journey of discovery!).
The VFD is inside a steel cabinet with specific fuses for the 3~ inputs on RST, so there is an additional layer of protection for the wiring and device there. I think I'll just give it a go with single phase to terminals R and S at incremental voltages from 12V to 415V and see how I get on.
Many thanks again for the various bits of information, Simon.