I am very sure that the original rollers from the boatyard would not be PEEK , due to its' very very high cost, although it would probably do the job fine.
I would not recommend any sort of PE or PP, UHMW or otherwise, as the loads on a mast truck can be quite high. It is not up to this sort of job.
You might try acetal resin, 10% glass filled + PTFE filled if you can get it. One brand is Delrin. It is an engineering resin and will carry high loads especially if glass filled, has low friction, is easy to machine, is commonly available all over the world, and costs far less than PEEK although slightly more costly than PE or PP. Acetal is not hygroscopic , despite what some people think, and is great for marine use. Nylon is hygroscopic and not best for marine use, as it absorbs water over time and will lose strength, possibly cracking in time.
When you make a replacement set, make an extra set the sailor can stow in a ziploc bag in the rigging locker just in case. It's only a few extra minutes once you are set up, and could make a big difference on a bad day at sea.
To ID the original rollers' resin, try some solvent glue / plastic cement / ABS glue on a small area. If the dried glue will not stick at all, the resin is probably acetal. If it sticks a little, it might be a plain or glass filled nylon. You can also do a melt test on a piece of the roller sitting on a steel plate with a thermocouple next to it. Heat from below, gently, with a small gas torch or lighter. If the sample melts at about 180 deg C it may be nylon or acetal. If it melts at over 320 deg C it may be PEEK or other exotic high temp resin, possibly PPS or PVDF.
Edited By Jeff Dayman on 27/09/2018 22:32:15