His drawing shows decimal degrees, so the angle is a little under 41 1/2 degrees. You can check it by doing inverse cosine of 18.75/25 .
The reason for writing is to suggest you think a little about your machining strategy. If you are driving along the straight bit towards your stopping point, as soon as you hit that point, the amount of cutter circumference engaged in the work increases drastically. At the very least, the finish on the part will be inconsistent.
It may be better to plunge cut the four tangent holes (perhaps with a 3/8" cutter) so the bulk of the material is removed before you drive into the corner.