I would feel inclined to turn the Acetal to length, or at least so that the ends are at right angles to the axis.
The tools need to be sharp, or they will rub and melt the material, similarly, if in doubt use a slow speed.and fine feed. The swarf and the finish will tell you whether you have got it right or wrong.
Then grip in the vice on the mill, using a Vee block, to hold the round Acetal vertical.. You can then mill along each side using the X and Y axis movements.to obtain the required size. (depths of cut are below )
The depth of each cut will depend upon how much (length ) grip you have for the raw material. If in doubt, err on the side of caution. Over ambition could equal "scrapper"
If the vice is too small to do this, than lay the Acetal horizontal in the Vice, and mill one side, removing half the material required to bring from raw size to finished size, in one plane. Say 0.681" or 17.3 mm
Rotate the Acetal in the vice, and using a square, set it up with the new flat face vertical, and repeat the original milling operation., again, removing half the difference between the 60 mm and the other dimension of the Aluminium tube. Say 0.431" or 10.95 mm.
Repeat the first set up and mill operation again, so that you should then have two sides the required distance apart, and parallel.
Repeat the second set up and mill operation, and you should have your round Acetal with a good fit in the rectangular Aluminium tube.
HTH
Howard