Posted by Karl Hundermark on 13/09/2022 18:31:19:
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I always have the fire extinguisher handy anyway…
I recommend a bucket of dry sand or – much better – common salt. Fire extinguishers are no good unless specifically designed to fight light metal fires. Titanium and Magnesium burn ferociously once they get going. Don't get rid of the fire extinguisher though – it will be useful if the fire spreads to the rest of the workshop!
Problem is Magnesium and Titanium are both more reactive than the Hydrogen in Water. If water is sprayed on to a Magnesium fire, the Magnesium burns by stripping Oxygen from the water and releasing Hydrogen gas. As Hydrogen is explosive, the result is a fireball that scatters burning Magnesium in all directions. Similar, albeit less violent, can happen with Carbon Dioxide, and CO2 extinguishers are also likely cause trouble by blowing burning swarf about.
This picture shows a professional fire crew getting caught out. Left blue circle shows a water jet, right blue circle identifies an unfortunate fireman up a ladder.
Fireballs are unlikely to happen in a home workshop unless a large quantity of swarf is allowed to build up. Up to 200g of swarf catching fire on a lathe could probably be controlled by a quick thinking operator with a bucket or two of salt handy. A ton of Titanium or Magnesium swarf on fire is a major incident likely to overwhelm the fire-brigade.
It's not the machining that's dangerous, it's more what happens when a pile of swarf catches fire as a result of machining nearby. So the less swarf on the machine the better. It's not rocket science – don't let swarf build up and be prepared for a fire just in case. In small-scale circumstances, I think the biggest risk is the shock of a small heap of burning white hot swarf panicking an unprepared operator into doing everything wrong and thus giving a small fire time to spread to the rest of the workshop.
Don't take any personal risks. Get clear and raise the alarm immediately after emptying the bucket – being overcome by fumes is very dangerous.
Dave