I have received much help from various forum members but usually I am not able to contribute much. After a working life on the chemistry side of the paint/plastics industry it is nice to find a subject I can perhaps usefully add to.
For oil-based paint, the usual paint-makers technique is to add a volatile anti-oxidant to the paint at the last moment before canning it off. Methyl Ethyl Ketoxime is the usual one. This additive prevents skinning in the can but it must evapourate quickly from the applied paint film or it will stop the paint from drying on the job.
All well and good, but if the painter has the can open for any length of time, the anti-oxidant will evapourate out of the paint left in the can – result: the remaining paint is going to skin over in the can. The bigger the air space above the paint in the partially empty can, the more pronounced this happening will be.
There are two techniques that can be used to stop this happening:
1. Decant the paint before using it, into a number of small containers, seal them tight and use these in turn. This is the most foolproof method
2. Cover the paint left in the can with something to stop air getting to it. Any of the suggested methods using clear film etc will work fairly well but the use of a solvent layer on top will only work if the paint can will not be moved about much after adding the solvent.
It also helps to be conciencous about cleaning around the lid and can rim to ensure a good seal.
However ONE POPULAR IDEA DOES NOT WORK and that is storing the paint tin upside down. If the conditions are met for skinning are present (i.e. loss of antioxidant, too much air above the paint) then the paint will do its thing and skin. The difference is that the skin will be below the paint when the can is opened. It then becomes very difficult to remove the skin without leaving bits behind that are difficult to remove entirely.
Please note that my comments only apply to oil-based paints
Chas