Hello Jerry,
Firstly using a silver alloy to join metals is usually refered to as "brazing" and is done at much higher temperatures than "soldering" with lead/tin alloys. Secondly I am assuming you are using the appropriate gauge/type of pipe and flat copper for the job.
You mention"a piece of 1.6mm copper sheet to 'cap' the tube off"
This method is usually only used to "cap off" a piece of tube and not for what might be construed as a pressure vessal or joint, in which case you should use a proper "pipe cap" which is a pressure fitting.
For copper to copper you dont need flux when using a 5% silver alloy rod, if you are using something like No 2 Flux (borax in water) then you will only mess up the joint.
Then you say "cleaned very bright with emery "
Good, hope you did inside and outside of the joint so that the brazing alloy can run around the inside of the joint too.
THEN !
"and played the propane torch all over the joints for several minutes before removing the flame and touching the stick.."
.AAAHH!!! Now this is perhaps where you are coming unstuck. Heating of the joint is good and application of the brazing rod is good BUT you should NOT take the heat away from the job, you need it to keep the job hot enough to continue melting the rod around the joint. OR do you mean you simply re-directed the flame to another part of the joint.
Either way I think I can safely say with reasonable surety that a propane torch will not provide the heat output required for silver brazing, it is usually used for "soft" soldering ie lead/tin alloys. I have not built model train boilers so some of you guys may have an "issue" with this statement.
Also the Bunnings site states that your torch " is ideal for medium joints, soft soldering, paint stripping, glazing, enamelling, jewellery, bending and tempering pipes, aluminium brazing, smelting light metals, freezing seized pipes, bolts and small forging work"
Regards Brian