In January 2019 Tim Stevens put the embrittlement more eloquently than I can.
“If I can add to the ’embrittlement’ idea:
This effect is known mainly on high tensile steel, and is caused when electroplating (such as zinc). When the steel is put under tension, hydrogen (from the effect of electrolysis) trapped under the plating percolates along the crystal boundaries of the steel, causing serious weakness. Just like a single drop of water can loosen the cohesion of a sugar lump.
If this effect happens in die-casting alloys in damp conditions, it may be because layers of different metals make tiny cells, generating small currents. This then creates the same sort of conditions as in steel. And the hydrogen comes from the water (even without electrolysis) as the metal – aluminium, zinc etc – reacts with moisture. This corrosion is called oxidation – the metal takes oxygen from water, and this leaves spare hydrogen ready to creep between the minute crystals.
The real problem is that neither the makers of model cars, nor those who made carburettors, or dashboard knobs, had any idea that their products would be treasured one hundred years later.
The same sorts of effects will destroy our favourite plastics, soon enough, don’t you worry.
Cheers, Tim “
Regards
Gray,