Your question was why you see a lot of advice not to use brass fittings in steam boilers, which I answered in a simple form, you didn’t ask what the various codes require, that’s a different question!
Yes many / most commercial boiler fittings do seem to be brass, why? I don’t know! Probably because brass is slightly cheaper. Having seen the result of dezincification on some of these, I don’t buy them but make my own. I have just finished a 3 cock gauge frame for my half size traction engine. I could have bought one for around £300 with no certainty on material or I could make my own. Material I had mainly in stock cost unknown now as purchased a long while ago but it’s all boxed up and marked so I know what it is. The stainless I was short of for the cocks was £8. My labour was effectively free but if charged certainly not economic as including plugs and copper washers there are about 20 separate parts in the assembly discounting the glass and seals so it took me about 24hrs to make. However it’s quite a satisfying thing to make and I know it’s not going to rot away any time soon!
The blow down valve I am also making from bronze and at 1/2” BSP with 120 psi behind it would be a fearsome lump of shrapnel if it parted company from the boiler.
As Jason says, pressure and temperature (and size) play a part in the decision on material. I am sure on your boiler, brass will probably see you out if you are not steaming it half the weekends in the year. But as to why brass is not the ideal choice, you have your answer.
Paul.