I’ve no hands on experience with 7 1/4″ gauge or any railway sleepers, but fwiw. I’ve broken and loaded trucks with multiple thousands of tons of both concrete road surfaces and sidewalks. Concrete is extremely strong in compression as long as it’s fully supported on a highly compacted crushed rock base material. It’s also easily broken in tension such as having any voids under it in that rail bed and then having heavy locomotives crossing above any unsupported areas. It’s a quite brittle material in it’s cured state, and in the right conditions easy to break. Adding steel as reinforcement and then cast the concrete around it would help a lot.
And concrete once cured isn’t a one type fit’s all uses material. Changing the rock and sand type and size, the cement in higher or lower proportions, how dry or wet the mix is, or even some of the more specialized additives used today in concrete can very much alter it’s strength, weight or amount of flexibility it will have before it breaks. One would assume your project is going to require hundreds if not thousands of those concrete sleepers. You really need to be asking a proper concrete expert your questions just to avoid any costly errors. Any batch plant that mixes and loads concrete trucks for delivery to the job site will almost always have at least one application expert that might be willing to advise you. Bringing a box of doughnuts or I guess in the UK, cakes along with you for your visit might help to get the best information and cooperation since I doubt your going to paying for or have any full concrete truck show up to load your probably limited amount of forms. You’ll also need to research the best release agent to apply to the inside of those forms so they can be easily released from the semi cured concrete and then reused. But concrete is also fairly expensive with usually a lot of time involved. Just like building a house, a strong and firm foundation isn’t optional. So the preparation below your rail bed and the bed itself is key. And that compacted rail bed absolutely requires a dry natural soil type under it as well. In construction, any soil that will allow plant growth is generally referred to in North America as a biological soil and none of it should ever be present anywhere below your rail bed because it’s seriously weak and has very poor compaction, any added water from rain will further weaken it even more. Without removing all of it and also ensuring good water drainage, both the rail bed and those sleepers will be guaranteed to fail given a bit of time. I hope some of this helps what your trying to do, or at least gives you a bit more detail about where to find better information than I can offer.