Like Mick Dobson, I was involved with I.C. engine manufacture and development for almost all my working life before retiring.
I would be very doubtful if you could find an adhesive/sealant that would withstand the temperatures to which the valves and seats are subjected at full speed, full load, To give you an idea of the temperatures, for many years, valves have used sodium cooled valve stems, and the valve seats are made of materials that cause experienced Methods and Production Engineers heartache to machine.
Despite the exhaust temperature being upwards of 700 C, the valve and seat temperatures will, even instantaneously be well above coolant temperature. And Air Cooled heads tend to run hotter than liquid cooled.
Believe me, if a valve seat comes loose, you will be very likely to find the only repair being to jack up the rocker cover and bolt a new engine under it!
Fit the valve seats by the "Heat and Freeze" technique (In industry the seats are frozen in liquid air or nitrogen before fitting and then pressed in). This assumes that the parent metal is of sufficient thickness to withstand the stresses from the interference.
If possible have the outer edge of the seat inserts overlap the cylinder wall, so that they can't fall into the cylinder. I have seen even the valve inserts (steel in an alloy head) staked, or even screwed in, come loose on air compressors, which run at much lower temperatures, and then they are not a pretty sight.
You are unlikely to run the engine for 50 hours non stop at full load rated speed, but a model aircraft, or powerboat, engine will run long enough to total itself if the seats come loose.
Months to machine and build, but a second to become scrap metal if anything goes badly wrong, so do be careful!
Howard