Whilst not disagreeing that the use of bronze for "fittings" (e.g the bits you can unscrew from the boiler) is a good idea Phil – it's not actually mandated in the Southern Feds 'Orange' book. Nor in fact is it mandated for mountings & bushes (e.g. the bits permanently attached to the boiler shell) – although I would be very unhappy if told by a prospective new builder that they intended to use 'brass' for such bushes – it is very poor practice these days and I would find it unacceptable.
However, the SF test code simply states that "The constructor of a boiler to other than a recognised design available through the model engineering trade and/or press shall produce design drawings and demonstrate to the satisfaction of the Inspector, either by calculation or by well-proven example, that the design and materials used have adequate strength." So to a large extent it depends on the inspectors view of things and is therefore subjective – and of course it could also be subject to the age of the boiler design being used (many older ones are a bit suspect!).
For context – there are many G3 locomotives in current use that I'm certain have brass 'fittings' and that are perfectly safe provided the regular inspections/tests are undertaken. I'm not aware of any of our boilers being failed for this reason. I'd be a lot more nervous about finding a non-captive spindle, as these are very dangerous to the untutored – and personally I would strongly recommend that the owner changed it as soon as possible (for a captive type). However, the Orange book clearly states that a non-captive spindle should NOT be a reason to fail the boiler!
My advice to you Phil would be to certainly use "known" materials for the bushes (and all permanent boiler mountings) in accordance with the BoM of the boiler design that you are building and if possible use your 'unknown' material in areas away from the heated water. It will then be much easier for your inspector to give your boiler the go ahead if there is no room for doubt.
I'm not making these points to be contentious btw, simply to re-assure owners of existing (especially older) small boilers that brass fittings are certainly not the end of the world. Keep an eye on things and if in any doubt change them. Bushes are more problematic (it's very hard to know what material has actually been used for a start) but again, the owner should know his engine and be aware of any signs that things may be going south – and if in doubt – ask his local inspector for advice.
Regards,
IanT