If you can find a scientific or technical/chemical glassware maker near you, ask them for a high pressure gauge glass of the diameter you need. They will likely have a selection in stock of tempered borosilicate glass disks. I know of one such firm, this side of the pond, but I’m not sure in UK.
Do not use polycarbonate in steam service at all. It will not take the temperature and even when cold will only take low pressures.
There are a couple of specialty translucent plastics that will take high temperature, but they are not steam service rated and are not to be used for pressure vessels and are VERY expensive. Solvay’s ‘Topas’ is one brand.
Glass, tough and thick, will do a good job in steam service at reasonable cost.
Just my $0.02. Your mileage may vary.
JD