Greetings Alan, I would suggest Citric Acid crystals for a copper boiler, flushed into the boiler with hot water through a safety valve bush, aggitated as much as practical, depending on size, allowed to cool, and well flushed with cold water.
About a heaped teaspoonful for a largest 3.5 in boiler, up to a heaped tablespoon for a large 7 1/4 gauge boiler.
Citric acid is safe to use & will not damage boiler fittings. Some people use drain cleaner etc, but its strong acid content can do damage, as well as being dangerous to use hot.
The residue can be flushed down the drain.
try a home brew shop for bulk supplies.
Regards
Leighsteamer