Both the shunts drop the same voltage at full current, 0.075 V This is not a lot in a 12 or 24 V system but the 100A will drop 0.0375 at your MCB rating of 50A . The description says the resolution is 0.1A for both so no advantage there.
Apart from lower voltage drop the 100A one will let you see if the current is higher than the MCB rating.
I’d get the 100A out of those two
If cost was no object I’d use a Hall effect sensor as they don’t drop any voltage (I have some in stock).