Ronan is correct – some Aluminium alloys contain a high proportion of silicon, and when the Al is eaten away (by eg washing soda, or worse, caustic soda) the Si is left as dirty smudges. This is a major reason why anodising does not give good results on such alloys.
Aluminium does not rust
It crumbles to a greyish dust
And most of all what you can see
Consists of Al two O three
Cheers, Tim