In addition to Robert’s points, two other things to take into account are:
It is a lot easier to drop a rocket than try to “throw” it off the top of the launch aircraft. The rocket drops like the proverbial stone. Have a look at a video of Orbital Science launching a Pegasus rocket from their Tristar.
The other point is a bit more esoteric. There are many videos showing how weapons dropped from an aircraft can fly back up and hit the aircraft, often inflicting serious damage. I suspect that falling free from a simple wing, as is the case for Virgin’s Mothership, is a lot cleaner than dropping from a conventional aeroplane, giving lower risk. A flight test to confirm safe release of stores from an aeroplane is part and parcel of weapon integration on an airframe.
Dave