I don't think it's cast in stone that you will actually need support for the vees. (If indeed they are vees rather than a circular section). It's surprising what you can get away with in this respect (try some of the test-pieces on Thingiverse).
In any event, if it were me, I'd first try, as a test, a single pulley section laid flat **, using a circular belt profile if that's feasible. and minimising the depth of the belt profiles as much as possible I'd keep the taper-angle for the vees as large as I reasonably could too
.I'd print this without support and see what happens.
For material, I would think ABS ould be preferable o PLA but ome of the more advanced materials (of which I have no experience) might possibly be better …. don't know.
Edit: ** Come to think of it, I'd just start printing the whole model and stop it if the first section is unsuccessful.
Edited By Peter Greene on 07/02/2021 20:04:14