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  • #4832
    Circlip
    Participant
      @circlip
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      #44951
      Circlip
      Participant
        @circlip
        Starting a new topic for this one, as, looking on another Forum the other day, it was suggested that a certain material was far more suitable for a given application than the norm in Toy sizes. What the poster ommited to mention, possibly due to ignorance of the material involved is that it is highly toxic and a LITTLE care is required in its use.
         
         One of the problems with todays education system is that the “I’ve got some spare time/cash so i’ll have a go at that” brigade have never or will, learn about the pitfalls of some methods and materials without some old fart giving them the Heads Up.
         
          Seen what happens to PTFE when you burn it ????
         
          First don’t SMOKE over the vapours, – you can DIE.
         
         Second, don’t touch the black sludge, it’s called HydroFlouric Acid, (Look that one up for Yerselves.)
         
          Oiled brown paper over the slides? Good idea, especially when you’re machining Titanium – NOT.  And Titanium is being used more extensively nowadays for Toys – cos it’s available. Have a read at the FLAMABILITY warnings, makes Magnesium almost safe. I read that another well respected old Fart has a large metal Baking tray clamped between his milling table and the vise, THAT stops turnings falling into the slots, easy to clean too.
         
          After having to ensure that ones workforce didn’t hurt themselves (Or the equipment they used, or THEIR workmates) in industry, whilst NOT trying to be a Galactic Guardian on safety, it is rather annoying when some glib gobby twits seem to regard it as second nature to everyone and scoff at attempts to EDUCATE those without the experiance of an engineering career to SOME of the pitfalls.
         
          Capt. Mainwaring and Cpl. Jones may find it amusing, but Fraser finds it sad.
         
          Regards  Ian.
        #44956
        David Colwill
        Participant
          @davidcolwill19261
          I have heard that some O rings can release hydroflouric if heated also I beleive that tufnol  can give off toxic fumes when machined. I am sure that there are many other nasty things lurking around that I am completely unaware of. While like most people I read and listen to any warnings and advice on these matters (and take them very seriously) most of my experience is gained from actually doing things which on reflection is not the best way.
          It would be an excellent use for this site, if it could have some kind of data base for materials and processes that pointed out some of the pitfalls, so that those of us who lack experience in some area could “gen up” beforehand . The fact that most of the articles have already been written and published should save some time. If only one serious accident were avoided it would be worthwhile.
          #44969
          Ian Abbott
          Participant
            @ianabbott31222
            ‘Kay, a few simple but nasty ones.
             
            Lacquer thinner, destroys brain cells, is both absorbed through the skin and inhaled. Always  wear a respirator with organic cartridges, gloves and full cover.  Also a fan blowing away from the user.
             
            N-hexane.  This is a light petroleum distillate.  Used in things like spray adhesive, it fries the myelin coating on the nervous system, leaving damage similar to multiple sclerosis. 
            I know this one from personal experience and it ‘aint nice.
            N-hexane used to be found on the MSDS sheets, until the chemical companies found out what it did.  Now, it’s just lumped together under the general heading of “Petroleum Distillates”.  Nice of them.
            Solvent cement used for joining plastic plumbing pipes can cause the same damage.  I’m not sure if it’s n-hexane, but the outcome is the same.
            Organic cartridge respirator, fan and gloves again for any stuff like this. 
             
            Fumes from arc welding are bad, as are soldering fumes.  Generally, moving air will suffice, respirators aren’t that convenient for this, but there are some nice, but expensive air flow helmets and visors.  Acid based soldering flux fumes can cause eye damage, I’m told.
             
            Off the wall one here.  Wash hands _before_  going to the loo.  Genital cancer is common in engineering circles.
             
            Ian
            #45160
            Paul Hanson
            Participant
              @paulhanson23918
              This is a very good suggestion – as someone who belongs to the spare/time cash, have a go brigade (although without either the time or the cash!)  I welcome this.
               
              Basic safety is a must and although I think I am fairly sensible in practical arena (machines etc) I have little knowledge on the materials side.
               
              Can I suggest that the administrators give this a category of it’s own that contains threads rather than being a thread – otherwise it’s visibility is only as good as when the last item was posted.
              #45205
              chris stephens
              Participant
                @chrisstephens63393
                Hi Circlip,
                Can I ask if you have personal experience of machining Titanium.
                chriStephens

                 
                 
                  Oiled brown paper over the slides? Good idea, especially when you’re machining Titanium – NOT.  And Titanium is being used more extensively nowadays for Toys – cos it’s available. Have a read at the FLAMABILITY warnings, makes Magnesium almost safe. I read that another well respected old Fart has a large metal Baking tray clamped between his milling table and the vise, THAT stops turnings falling into the slots, easy to clean too.
                 
                  After having to ensure that ones workforce didn’t hurt themselves (Or the equipment they used, or THEIR workmates) in industry, whilst NOT trying to be a Galactic Guardian on safety, it is rather annoying when some glib gobby twits seem to regard it as second nature to everyone and scoff at attempts to EDUCATE those without the experiance of an engineering career to SOME of the pitfalls.
                 
                  Capt. Mainwaring and Cpl. Jones may find it amusing, but Fraser finds it sad.
                 
                  Regards  Ian.

                 

                #45207
                Circlip
                Participant
                  @circlip
                  YES
                  #45209
                  chris stephens
                  Participant
                    @chrisstephens63393

                    Hi Circlip,

                    Then you should know better, and you are wrong about comparing Titanium with Magnesium. 
                    chriStephens
                    #45212
                    David Clark 13
                    Participant
                      @davidclark13
                      Hi There
                      Never had a problem with titanium even with heavy metal removal. 100 thou cuts.
                      Now magnesium, I machined a wheel once, (car) and it was just spotface deeper.
                      Started to burn – swarf decided to catch fire.
                       
                      Someone shouted turn the soluble on.
                      Big Mistake!
                      Oxygen in the soluble helped combustion.
                      So if you set magnesium (or titanium) on fire, make sure you have abucket of sand handy.
                      regards David
                       
                       
                      #45224
                      mgj
                      Participant
                        @mgj
                        I must admit I’ve never had a problem machining Ti. I don’t like the stuff as a material, and one has to be very careful about surface finish if it is to be in a stressed application., you just have to keep it cool as has been suggested, (lots of coolant) and clear the swarf.
                         
                        Magnesium is, as has also been pointed out, a bit more interesting – both to weld and machine.  Its Ok if you do it under argon.. Pays well.
                         
                        I think I’m OK on this one – about engineering careers. One ordinary degree (sort of – long story but all sorts of bits and bobs to do with tanks), one MSc, (guidance and control theory, propulsion, and aerodynamics , strengths of materials, mechanics, warheads and so forth) and a while spent at military experimental estabishments fiddling about with guns, motors and armour and other bits and bobs at trials units,  – mine plough, odds and sods in the IR spectrum in thermal imaging, fire control equipment, oh and even some of the new depeleted fin ammunition in its ealry guises – and a little while in Defence Quality Assurance. policing other peoples engineering.Brit Steel castings at Sheffield,Bavid Brown Gears, Commercial Hydraulics(gearboxes and variable swashplate motors used as double differentials), Rolls Royce(Perkins), plus Vickers at Newcastle and Royal Ordnance as was, at Barnbow in Leeds. So one was expected to know what one was on about.
                         
                        ————-
                         
                        O rings and hydrofluoric acid. Quite willing to stand corrected, but I believe the problem is limited to Viton rings, and only if they are used outside the recommended temperature range. Like all things there is a tech spec and that spec should not be exceeded without being certain of what one is doing. .
                         
                        If you get down on your knees and ask for touble, don’t be surprised if it visits you in full measure.

                        Edited By meyrick griffith-jones on 17/11/2009 18:50:49

                        #45225
                        chris stephens
                        Participant
                          @chrisstephens63393

                          Hi Meyrick,

                          Even with all that experience behind you, I bet you got more of a thrill out of  getting your traction engine running.
                          On the subject of dangerous products of combustion, even AA men are warned about not touching some of the burnt rubber (viton?) components after a vehicle fire, for that very reason. Forewarned is forearmed, doesn’t say you can’t touch the rest of the car, though.
                          chriStephens

                          Edited By chris stephens on 17/11/2009 19:33:07

                          #45226
                          mgj
                          Participant
                            @mgj
                            Some was plainly a lot of fun, some was grimly satisfying, when one had forced a rectification – brittle martensitic transition in stainless welds on ferritic armour.  But yes – your own thing after so long. Even if it did need a helping hand for its first start. Yes, it was OK.
                             
                            Worth all that coffee.
                            #45228
                            ChrisH
                            Participant
                              @chrish
                              “Can I suggest that the administrators give this (materials and their possible evils! CH) a category of it’s own that contains threads rather than being a thread – otherwise it’s visibility is only as good as when the last item was posted.” – from Paul Hanson.
                               
                              Paul, I’m with you on this – a damn good idea, would be very illuminating, informative and advisory.
                               
                              ChrisH 
                              #45235
                              Circlip
                              Participant
                                @circlip
                                Another thread in danger of being hijacked by the intrusion of Stan and Ollie, however, good points by Paul H and Chris H so what about it D C??? and just to clarify for those who are able to listen and note, the guys who HAVE had Ti. fires will tell you that it DOES burn as fierce as Magnesium.
                                 
                                  Cautionary regards  Ian.
                                #45239
                                Windy
                                Participant
                                  @windy30762
                                  Regards Viton products in vehicle fires when I was in the motor body repair trade we had warnings about the hazards. Look at the HSE site now about the risks it makes interesting reading.   
                                   
                                  Windy
                                  #45246
                                  David Clark 13
                                  Participant
                                    @davidclark13
                                    Machining materials new thread is here.

                                    http://www.model-engineer.co.uk/forums/threads.asp?t=173

                                    Edited By David Clark 1 on 18/11/2009 08:19:45

                                    #45249
                                    ChrisH
                                    Participant
                                      @chrish
                                      Thank you for that David.
                                       
                                      ChrisH 
                                      #45251
                                      Niloch
                                      Participant
                                        @niloch

                                        A very good idea David.  Would it be possible to (a) insert some sub-divisions into the thread, e.g. brass, cast iron, stainless steel etc so that the information would be more readily available; (b) copy and paste SOME of the above into the new thread?  I suspect that there are large numbers of model engineers who are never likely to want to machine magnesium, depleted uranium, osmium,  frozen chewing gum etc. so please be selective as to the quantity of posts copied and pasted regarding the more exotic materials; (c) don’t let’s forget the non-metals, plastics; natural materials antique ivory or its substitute, bone etc.

                                        #45252
                                        David Clark 13
                                        Participant
                                          @davidclark13
                                          Hi There
                                          No way of introducing sub categories.
                                          If any one would like to copy mesages over please do.
                                          I don’t have the time.
                                          regards David
                                           
                                          #45259
                                          Circlip
                                          Participant
                                            @circlip
                                            Thanks David.
                                            #45270
                                            chris stephens
                                            Participant
                                              @chrisstephens63393

                                              Hi Circlip, (and anyone who wants to know more)

                                              I do wonder why you mentioned on a model engineering forum the fire potential of Titanium and the risk involved with oiled Kraft paper, most model engineers will, most likely, have never seen or touched Titanium let alone machined it. Industrial machinists would have no need of protecting their mill tables in such a way, and they would or should know how to handle such “exotics”! If a large mass of Titanium does catch alight, through carelessness, the paper will be the least of their problems.The new listing of machining materials, will help to educate those wishing to use some of the more exotic materials.

                                              For those unfamiliar with Titanium, it is a light weight non rusting metal, it is easy to machine PROVIDED you don’t let the tool rub. If you think Stainless work hardens, it is as nothing to Titanium! Titanium will almost “spontaneously” combust, if provoked but read more further down. Quite a few non professional designers ask for it thinking it is the answer to all their weight and strength problems, WRONG. What they really need is a metal called “Unobtainium”, but that is another topic.

                                              Now for those interested in some personal experiences;-

                                              In a Titanium fire, what happens is it smolders brightly, very pretty but if one does not let the shavings built up to any great extent it is only a minor inconvenience. Granted one must be aware of the risk, but Magnesium is in a whole different ball game. When Magnesium burns the temperature is so great that water, put on it to quench the fire, can be split into Hydrogen and Oxygen thus fuelling it, hence the use of sand in wartime fire drill. A few shavings of Titanium can virtually be spat on, that’s if they don’t just burn themselves out before you can think about it. Moral is, don’t let them build up to a critical mass. Magnesium and Titanium are similar in that they both emit a brilliant white light when burning, but their rate and ease of combustion are somewhat different.  If you have had a serious Titanium fire, you must be remarkably clumsy or careless !

                                              Titanium burns because it has a very bad ability to conduct heat, so the temperature is maintained once built up by friction until there is enough heat to cause combustion. Clearing shavings prevents this happening, as does sufficient coolant. To demonstrate the effect to “newbies” I often put a bundle of Titanium swarf on the ground and light it with a gas torch, as I said it smolders and then goes out, but it is fun to watch the smolder run along a filament, but is it dangerous in that situation, not at all. The metals lack of heat conduction seems to prevent the heat escaping, to the surrounding. It does teach the said newbie of the risks though. In my opinion, plain ordinary wire wool is far more dangerous; there just a spark from a grinder can set it off, something that will NOT happen with Titanium. Do you have wire wool in your workshop, well I hope you keep it in a tin, lest those pesky little sparks contrive to spoil your day! If you really want a fire risk, you could not do better than use a Linisher to remove rust and then grind some Aluminium, in case you don’t know, that makes a compound called Thermite, look up the risks involved with that!

                                              This morning I did another firing of some Titanium shavings, a small bundle about the size of an egg. (I keep some handy especially for demonstrations)  I lit it with a gas torch, as per usual, and sure enough a very bright light, but it soon went out. I then lit it again, more bright light and then it went out again. I had to light it fifteen, times at different points, before it all oxidized. Now I am not saying you want this to happen by accident on your precious machinery, you don’t! Certainly a large mass of shavings or swarf, once alight, could really spoil your sunny disposition, so don’t let it happen. 


                                              The astute amongst you will of course point out that the shavings were cold before the fire, so the rate of combustion was slower than if they were hot and fresh off the lathe.  As I said Titanium has a very bad ability to conduct heat, so once hot from

                                              #45283
                                              mgj
                                              Participant
                                                @mgj
                                                If I may suggest it, this one needs putting to bed, because we are in danger of a lot of misinformation, being offered as opinion.
                                                 
                                                So a few facts.
                                                 
                                                Ti is a medium weight metal (sorry Chris but we agree on most else) whose density is about 2/3rds that of steel and which gets is reputation for light weight, not because its density is low, but because it offers a very high stiffness to weight ratio. Thus, if you get your stress engineering and notch control right, you can use it in relatively thin sections.
                                                 
                                                Like most metal, from sodium, and calcium onwards though iron, lead and uranium, ti will burn – that is to say oxidise rapidly, given sufficient heat and oxygen.
                                                 
                                                However, Ti comes from a totally different part of the periodic table from sodium and magnesium, and by definition will behave in a completely different and less energetic way. There is no possible way that it can burn like magnesium because its
                                                 bonding properties say it cannot.
                                                 
                                                Unlike magnesium and its close relative sodium, it is most unlikely to burn and continue burning, and the products of cmbustion/oxidisation are an inert white powder. Magnesium of course produces a hydroxide, which is caustic and very similar in behaviour to sodium hydroxide, otherwise known as caustic soda. So that tells you something about the characteristics and energy outputs involved
                                                 
                                                Now because of its resistance to burning and heating ,  – it is frequently used on the leading edges of the wings of supersonic aircraft and missiles, and on the noses of guided weapons which operate at very high mach numbers. Further if you look at some fires involving both Ti an Al, the ali has burned in the presence of a fuel, (such as Avtag or Avcat), but the Ti has not. In short, you are more likely to get a fire turning aluminium than you are Ti, and I am not aware of any dire warnings being issued about Ali.
                                                 
                                                Equally were there any significant risk of fire during machining, I would point you to BAe Filton who used CNC machinery to machine the engine frames of Harriers. These were quite complex frames consisting of the outline of the air intakes and the engine front hanger – 3 big holes and 2 stubs like a figure of 8 +. these were hacked out of  a solid chunk of  4″ thick Ti. There were no special fire precautions – indeed the machine was largely unattended.
                                                 
                                                So engine frames, nosecaps and the periodic table.
                                                 
                                                Someone somewhere is getting a little wide of the mark.
                                                 
                                                Ollie.
                                                 
                                                 

                                                Edited By meyrick griffith-jones on 18/11/2009 18:32:01

                                                #45284
                                                chris stephens
                                                Participant
                                                  @chrisstephens63393
                                                  Hi Meyrick,

                                                  Guilty as charged, but in my defence I was using the term as a comparative not absolute one. When compared to most metals that are used by hobbyists, barring Aluminium, it is “light”.

                                                  A minor thing to quibble over, compared to the main point, I think you will agree.
                                                  Glad to let the whole matter drop, then I can get back to making things.
                                                  Who is “Ollie”?
                                                  chriStephens
                                                  #45311
                                                  mgj
                                                  Participant
                                                    @mgj
                                                    I believe that you and I were referred to as Stan and Olly, and I opted for Olly because
                                                     
                                                    a. I got in first.
                                                    b. I am more likely to be the more spherical.
                                                     
                                                    Initially I thought it a rather ill mannered and trivial point – manners making the man? I don’t think that either of us have resorted to pointless personal jibes – but at the end of the day I don’t think mind being compared to a genius in his field. 
                                                     
                                                    Density of Ti. Fair enough. I only put it that way because many think its a sort of super ali, and are quite surprised to find just how heavy it is. (In absolute rather than relative terms)
                                                     
                                                    Ollie. 

                                                    Edited By meyrick griffith-jones on 18/11/2009 23:33:02

                                                    #45313
                                                    chris stephens
                                                    Participant
                                                      @chrisstephens63393

                                                      Hi Ollie, 

                                                      I get you now, I had not realized that some one would think of the two of us as a double act, let alone to use such a complimentary one. I can’t say I pay too much attention to some posts. You would have thought if he had intended to be pejorative, as I would have expected since he seems to disagree with most things, he would have picked a pairing more akin to say Hitler and Himmler or Burke and Hare.
                                                      I’ll settle for Stan, just don’t flutter your tie in my direction, unless you mean it.
                                                      A very complimented and flattered Stan
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