Chris,
A steam engine is different to an internal combustion engine in many ways. Even the basic analogy of a gas expanding behind a piston breaks down because ‘steam’ (unless superheated) is a vapour and it has the property of both condensing and evaporating at different points in the cycle. the biggest differences are:
The pressure on the piston doesn’t rise to a maximum at ignition, then fall. Instead when the valve opens it rapidly rises to maximum and (assuming the steam passages are big enough) stays more or less constant until cut-off, when the pressure starts to drop. This longer, steadier push (and the eas of making the pistons double acting) is why steam engines generally have fewer cylinders than petrol engines. A V12 steam engine would be pointless.
Secondly, there’s the influence of a condenser, if fitted. Very few model steam engines have condensers and the only one I have come across more than basic details of was by Tom Walshaw. The condenser takes the exhaust and literally condenses the steam back into water in an airtight box, out of which it pumps the water. Now, if the condenser was perfect and the steam contained no air, you could get a perfect vacuum, adding an extra 15psi or so to the difference between steam pressure at each end of the engine.
Even though this can’t be achieved in the real world Walshaw’s condenser was still effective enough that it allowed his engine to run steam at LESS THAN ATMOSPHERIC PRESSURE! That means a partial vacuum even in the steam chest and boiler, so the boiler was boiling at less than 100 degrees!
Try doing something like that witha pertrol engine…
The theoretical maximum efficency of a heat engine is determined by the temperature difference bewteen the ‘input’ and the ‘output’. Another way of looking at a condenser is that it is ‘refrigerating’ the exhaust, and hence it increases the efficiency by allowing greater power to be extracted from steam at a given input temperature (and pressure).
This is why Watt’s condensing engines were such a revolution.
I won’t get into superheat in detail, but you can easily see that /raising/ the input temperature is another way of increasing efficiency.
Neil