Where to start with this…
Has the boiler been hydraulically tested? There are good reasons for not testing it with air, and if it hasn't been tested you should not be putting 100psi into it.
100 psi is much too high a pressure for testing a small engine with no load. You will damage it. If it is a new engine and very stiff you might need 50 psi to shift it initially, but 20-30 psi should be plenty. If you have a pressure regulator on the compressor, start at the lowest pressure and increase gradually.
If it won't run at 100psi, then there is something wrong with the engine. Even if the compressor is too small to run the engine continuously, it should start and run until the pressure in the tank drops off.
Bear in mind also that the engine will need lubrication, especially the cylinders and valves.
Edited By Redsetter on 31/12/2022 17:07:06