Hi, Martin.
It seems you are making PCBs on a professional basis – mine are just for hobby use, although I have been doing them for a long time. I use the traditional etch method with a 'bubble' etch bath, but I now have a small CNC router which I intend to try and use for milled boards – reason being I have a box full of 'rejects' over the years using the photosensitive etch method, and they are scrap unless I use a different method. I find 'spray-on' photolacquer is pretty useless. I was making limit switch boards for this router when I made my mistake and noticed this effect.
I have etched one of the boards – its definitely 'reversed'. I will try to get some photos, but my camera is giving me trouble, so I can't produce good close-ups immediately.
For info, my lightbox has 4 x 14 Watt tubes covering an area about 5mm less than A4 dimensions. It is made by Gie-tech GmbH in Germany. I usually use genuine Bungard photo-sensitive glass-fibre board, usually 1.5 mm thick, both single and double sided.
The effect is reproducible – I tried again this afternoon, and it did the same thing. I also tried the transparency both ways up, to see if anything was transferred to the board, or a chemical effect, but no difference. I also tried, as you suggested, putting a sample in the box without the UV light on, and nothing happened.
I did think that it was possible that if the ink on the transparency was not fully dry, it could transfer to the board, but on second thoughts, the copper which is now 'exposed' is under the ink, so when it is etched, it disappears – if ink was transferred to this area, it would at least hinder etching, if not stop it altogether – so its very puzzling.
I appreciate your interest and efforts, and of your colleagues, to find an answer – I must admit I am thoroughly stumped – its going to keep me thinking for a while yet. If I come up with anything, I'll add it to this thread and 'bump it up'
Just an idea, since it is reproducible, if the 'inverted' effect, however it happens, could be fine-tuned to produce fine detail, it would be a simple way to produce a double-sided board from a single transparency! – I might get rich yet!
Best Regards,