Posted by JA on 24/07/2021 13:16:55:
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Some organisations, even respected ones, believe that the money representing the cost of opening this mine and the saving of transport costs (at present metallurgical coal is shipping into the UK) would be better spent developing a carbon neutral method of making iron.
Question – Is this possible?
Yes. Iron is a reactive metal and the ore, which comes in many forms, is mainly Oxides and Carbonate, plus many impurities. Steel makers go to considerable trouble to remove unwanted elements, including Silicon, Phosphorous, Manganese, Cobalt, Magnesium, Sulphur, Copper, Nickel and Calcium. However, the main problem is removing Oxygen. This is usually done by reducing the Oxide or Carbonate with Carbon: at high temperatures Oxygen has a higher affinity for Carbon, so Oxygen transfers producing Carbon Monoxide leaving more-or-less pure Iron behind.
Although any Carbon will reduce iron ore, it pays to use high purity coke, which is made from particular types of coal. Early iron-makers used Charcoal made from wood and many miserable failures resulted from using the wron sort of coal.
However, though metallurgical coke is cheap and clean for steel-making, any reducing agent would do, though many of them are toxic and expensive.
Of the likely future methods I guess electrolysis holds most promise. It's already used to make any metal more reactive than Iron such as Aluminium, Magnesium, Sodium, Potassium, Lithium, Scandium and Titanium etc.
About a third of the world's steel is produced electrically by melting scrap. Same job could be done with coke but electricity makes purer steel that's more profitable.
Until recent times Coal was the cheapest way of making Iron and Steel. The cost advantage will fade over the next century or so, but Global Warming is pushing it out too. The world is moving towards 'polluter pays', and burning coal would be expensive if wasn't dumped for free into the atmosphere. Fortunately there are alternatives, though I suspect steel prices will be higher in future.
Most chemical conversions in any direction are possible provided energy is available.
Dave