I have tried to silver solder stainless, with the right flux it can be done but I would not recommend it. TIG welding is the way to go with stainless, it is easy to do and provided there is no gap, you often don't even need filler. I found when making tanks for my steam launch that flanges are not needed, in fact they are a liability, and a corner will weld very nicely.
If your piece is shaped like I think it is, I would look for piece of tube the right size and the length you want the flange, and cut a piece of flat to match. Then I would Tig weld around the edge.
John