Rik,
The ciggy lighter thing and your gas tank build, the butane vp is goverened by a number of factors including liquid volume, temperature ambient and temperature max achievable….(external heat source e.g heat from your boiler)
There comes a point at which the vp cannot increase any further either by increasing the temperature or by lack of liquid volume allowing boil off…
Imagine a car engine, leave the rad cap off, the water will boil at 100C, replace the cap, increase the rad pressure, the boiling point goes up ( by how much? Take a look at steam tables )….
Edited By John Rudd on 24/09/2016 13:23:09