Hi Colin, not the easiest thing to do if you are inexpearienced but a few pointers are as follows:-
Brass is fairly easy and if you machine it it will cut with fine swarf that is in small pieces
Gunmetal, look at the bar it usually has a slightly speckled appearance — not definative only a guide, it is generally softer than brass and adifferent colour
Bronze is a coppery colour but much harder than copper
Ally bronze, almost identical in colour to Admiralty brass — nice yellow colour but it is much harder to machine and the swarf comse off in spiral or contiuous string [assuming you are not using a chip breaker] The outside of the bar willl probably not show the oxidation associated with brass.
Beware of Aluminium bronze it generally does not make good bearings but it is highly corrosion resistant.
Hope this helps a little
John