Knowing a bit of chemistry might clear some fog.
The Paraffins were a family of chemicals containing only Hydrogen and Carbon in single chain molecules. In modern Chemical parlance, they are called Alkanes.
The chains can be very long, and although the chemistry of all the members is similar, as the weight of the molecules increases, they go from gases to solids, via vapours, light liquids, heavy liquids, greases, sticky goo and waxes.
The first 4 are all fuel gases, delivered as compressed liquids in cylinders.
The heaviest alkane listed by Wikipedia is Tetrapentacontane (C54H110), a solid which boils at just under 600°C. Might find it in Bitumen.
Heavy Alkanes dissolve in lighter Alkanes, so the lighter liquid mixtures are often used as solvents.
Petrol, Naptha, White Spirit, Paraffin, Jet Fuel and Heating Oils are all mixtures of nearby Alkanes, where each group is heavier than the one below.
Petrol contains, amongst other things, mostly very light easily vaporised alkanes like Octane. An excellent solvent, but best avoided because the fumes are poisonous and a serious explosion risk, easily ignited by a static spark.
White Spirit is a mixture of Alkanes between Nonane (9 carbon atoms) and Dodecane (12 carbon atoms). The members are still light Alkanes, but much less easily vaporised than petrol. White Spirit is safer! The heaviest member (Dodecane) boils at -9.6C, so White Spirit shouldn't leave much residue behind.
Paraffin (aka Kerosene) is some mixture of the 14 Alkanes between Hexane (6 carbon atoms) and Icosame (20 carbon atoms). Hexane is highly volatile, making paraffin easier to light, but otherwise Paraffin's Alkanes are heavy, making Paraffin unlikely to be an explosion hazard in normal circumstances. Jet Fuel and Heating Oil are heavy paraffins, a tad safer again.
As all three are imprecise mixtures, there's no reason to assume that two different brands or even batches from the same maker will be identical. Also, because of the way they're made, it's like as not that a proportion of heavier Alkanes will also be dissolved in the mix as well. Mixtures like White Spirit which are intended to be used as solvents should be much cleaner, but there's no reason for Fuel Oils to be particularly fussy – used as a fuel, any heavier alkanes dissolved just get burnt with the rest. If paraffin is used as a cleaner, no surprise to find it leaves a greasy mess behind. Diesel fuel is even worse.
Bottom line, Paraffin is OK for a cheap rough clean, but White Spirit is a better, cleaner, solvent when performance matters, but it has no anti-rust properties.
WD40 is a more sophisticated mix: alkanes are only one member of the Hydrocarbon family, and chemists use them and other additives to tune products to particular goals.
Dave
Edited By SillyOldDuffer on 24/03/2022 16:39:21